Tunable electrocaloric and energy storage behavior in the Ce,Mn hybrid doped BaTiO3 ceramics

The electrocaloric effect and energy storage property are tuned in the Ba_1-xCe_xTi_0.99Mn_0.01O₃ ceramics prepared by the solid state reaction method. The ceramics with lower Ce content (x?=?0.005, 0.015) show a better ΔT and ΔT/ΔE response. The ceramics with higher Ce content (x?=?0.030, 0.040, 0.045) represent the broader ΔT peaks (50?K–60?K), and the higher energy storage density and efficiency. The largest electrocaloric response (ΔT_max?=?1.22?K, ΔT/ΔE?=?0.41?K mm/kV) is found in the Ba_0.995Ce_0.005Ti_0.99Mn_0.01O₃ ceramics, which is comparable or even higher than that of the most isovalent substituting BaTiO₃-based ceramics reported before. The maximum energy storage density 0.11?J/cm³ (E?=?30?kV/cm) is obtained for the Ba_0.970Ce_0.030Ti_0.99Mn_0.01O₃ ceramics, with high efficiency of 65–88% over a wide temperature range of 72?K. This work may open more opportunities to design high electrocalaric and energy storage performance lead-free systems from the viewpoint of the heterovalent and size mismatch substitution.     

CO2对油田地下水环境中Q235钢和X70钢腐蚀行为的影响

为了探明辽河油田地下水环境中CO₂对Q235钢和X70管线钢的腐蚀规律,采用动电位极化技术及交流阻抗技术研究了不同CO₂浓度对该环境下两种钢腐蚀行为的影响,并利用光学显微镜对试样腐蚀界面进行表征。结果表明:随着CO₂浓度的增加,Q235和X70钢的交流阻抗图谱的半径均减小,腐蚀电流密度增大,腐蚀坑数量、深度和面积都增加,腐蚀敏感性增大。在低浓度CO₂环境下(CO₂含量为10%时),Q235钢的腐蚀敏感性比X70钢更高;而在高浓度CO₂环境下(CO₂含量为20%、40%、60%时),Q235钢的腐蚀速率反而较小,耐腐蚀性更好。     

Anomalous crystal structure of γ" phase in the Mg-RE-Zn(Ag) series alloys:Causality clarified by ab initio study

The crystal structure of the single-unit-cell thickness γ " phase,as a key strengthening phase in Mg-REZn(Ag) series alloys,has been extensively studied,and several structural models have been proposed in the past two decades.However,these reported models,and even the lattice constants at the same proposed structure,are scattered severely,which has led to considerable confusion and not available for further mechanical property simulation and prediction of Mg alloys containing this phase.In this study,by using first-principles calculations,the crystal structure of y" phase is clarified,resolving the discrepancies among different experiments,and its intrinsic mechanical properties have also been studied for the first time.It is verified that the γ " phase contains quasi-five atomic layers,instead of the previously reported tri-layer,and surprisingly,its crystal structure has many variants,which would change with the alloy composition.Besides,with the help of the simulated selected area electron diffraction(SAED) patterns,it is found that the atoms in the central layer remain partially ordered distribution,and this ordered extent primarily depends on the atomic ratio of RE:Zn(Ag) and the solute content in an alloy.That is,the ordered extent increases with decreasing the atomic ratio of RE:Zn(Ag) and/or increasing solute content of alloy,and vice versa.Ag and Zn dissolved in the γ" phase would produce almost opposed mechanical anisotropy for the γ " phase under the identical crystal structure,and the addition of Ag shows more efficient on increasing the shear modulus of γ" phase.     

Rethinking Nano‐TiO2 Safety: Overview of Toxic Effects in Humans and Aquatic Animals

Titanium dioxide nanoparticles (nano‐TiO₂) are widely used in consumer products, raising environmental and health concerns. An overview of the toxic effects of nano‐TiO₂ on human and environmental health is provided. A meta‐analysis is conducted to analyze the toxicity of nano‐TiO₂ to the liver, circulatory system, and DNA in humans. To assess the environmental impacts of nano‐TiO₂, aquatic environments that receive high nano‐TiO₂ inputs are focused on, and the toxicity of nano‐TiO₂ to aquatic organisms is discussed with regard to the present and predicted environmental concentrations. Genotoxicity, damage to membranes, inflammation and oxidative stress emerge as the main mechanisms of nano‐TiO₂ toxicity. Furthermore, nano‐TiO₂ can bind with free radicals and signal molecules, and interfere with the biochemical reactions on plasmalemma. At the higher organizational level, nano‐TiO₂ toxicity is manifested as the negative effects on fitness‐related organismal traits including feeding, reproduction and immunity in aquatic organisms. Bibliometric analysis reveals two major research hot spots including the molecular mechanisms of toxicity of nano‐TiO₂ and the combined effects of nano‐TiO₂ and other environmental factors such as light and pH. The possible measures to reduce the harmful effects of nano‐TiO₂ on humans and non‐target organisms has emerged as an underexplored topic requiring further investigation.     

中国观念艺术发展症候分析

中国观念艺术三十多年的发展,是一场"没有坐标的运动。"中国观念艺术曾在一定时期和范围内偏离了人本主义思想的轨迹,没有沿着健康的道路发展。本文将从"后殖民化"与"本土化""智力"与"智慧""大众"与"精英"三悖论,对中国观念艺术发展的症候进行分析。     

陵水17-2气田完井液与储层保护技术研究

陵水17-2气田储层属于高孔高渗砂岩气藏,存在一定的盐敏损害。室内分析了储层盐敏损害因素,针对现场使用的高矿化度盐水完井液进行了模拟评价。结果表明,陵水17-2气田储层盐敏损害机制主要为矿化度变化带来的微粒脱落运移造成的渗透率变化以及可能存在的流体不配伍带来的结垢因素。甲酸钾完井液对陵水17-2气田投产效果影响不大,具有良好的储层保护效果,可满足现场作业要求。     

主井井塔双梁吊钩桥式起重机安装

曲江矿井主井井塔+54m平台上,需安装1台Gm=32/5T型电动双梁吊钩桥式起重机。由于吊装高度较高,空间狭小,井塔封屋顶面期间,在屋顶面预留400mm×400mm小孔,作为+46m平台的提升吊装孔;在屋顶面中间预留600mm×600mm小孔,作为+54m平台吊装孔。吊装时,先吊装左梁,再吊装右梁,小车正好落在组装好的左、右梁轨道上;然后将起重机推到机房中间位置,进行调试,完成安装。     

连铸机二冷设计中喷嘴的选择和测试

从连铸机喷嘴的分类入手,对各种喷嘴的特性进行了简要说明并结合研究实践,对某板坯连铸机选用的D25型系列喷嘴的测试做了探讨,包括测试内容、测试结果以及高差对水喷嘴喷水量的影响情况等。